Insight into the structure of supported palladium catalysts during the total oxidation of methane.
نویسندگان
چکیده
The combination of in situ X-ray absorption spectroscopy, X-ray diffraction and on-line catalytic data provided insight into the structure-performance relationship of a flame-made Pd/ZrO(2) catalyst during the total oxidation of methane: upon heating, a sudden reduction accompanied by sintering of the Pd-particles, leads to a significantly lower catalytic activity and a hysteresis during cooling down.
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ورودعنوان ژورنال:
- Chemical communications
دوره 44 شماره
صفحات -
تاریخ انتشار 2007